Azo Grubu İhtiva Eden Pirimidin Halkalı Schiff Bazı ve Metal Komplekslerinin Sentezi, Karakterizasyonu, Antibakteriyel ve Antioksidan Özelliklerinin İncelenmesi

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Thesis Type: Postgraduate

Institution Of The Thesis: Van Yüzüncü Yil University, Fen Bilimleri Enstitüsü, Kimya (Yl) (Tezli), Turkey

Approval Date: 2013

Thesis Language: Turkish

Student: Kübra Baysal

Supervisor: Mehmet Gülcan

Open Archive Collection: AVESIS Open Access Collection

Abstract:

In this study, derived from N-Aminopyrimidine-2-one and 5-((4-ethylphenyl)diazenyl)-2-hydroxybenzaldehyde compounds pyrimidine linked monoazo Schiff base ligand (HL) has been synthesized. The complexes of the azo Schiff base ligand were synthesized with metal salts of Cu(II), Ni(II), Mn(II), Zn(II) and Pd(II) in the general formula of [M(L)2]nH2O complexes were in the octahedral structure, and [Pd(L)2]?2CH3COO complex was in the structure of square plane. The structure of the synthesized ligand and metal complexes were determined with elemental analysis and spectral techniques such as FT IR, 1H NMR, 13C NMR, UV-vis. In order to determine the spectral techniques above-mentioned molar conductivity, magnetic susceptibility measurements and thermal analysis were used. In addition to, all of the synthesized compounds electrochemical and biochemical properties such as antibacterial, antifungal and antioxidant were also investigated. Key words: Azo Schiff base, N-aminopyrimidine-2-one, metal complex, electrochemistry, biochemical activity.