The template synthesis, characterization, and thermal investigation of new Heterocyclic binucleating Schiff base complexes

Sonmez M., Sekerci M.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.34, sa.9, ss.1551-1561, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 34 Konu: 9
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1081/sim-200026585
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.1551-1561

Özet

1-Amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one (L'H-2) reacts with benzil (L"O-2) and salts Cu(AcO)(2) . H2O, NiCl2 . 6H(2)O, CO(ACO)(2) . 4H(2)O, CdCl2 . 2H(2)O in 2: 1 : 2 molar ratio in n-butanol to give several solid complexes of the general composition [(M)(2)(L')(2)(L")(X)(4)] . nH(2)O. The precursor and the metal complexes of the Schiff base have been characterized by elemental analyses, molar conductances, IR spectra, electronic, and thermal studies.