Manganese(III) acetate promoted acetoxylation of various alpha,beta-unsaturated cyclopentanones


TANYELI C., Tosun A. , TURKUT E., SEZEN B.

TETRAHEDRON, cilt.59, ss.1055-1058, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 59 Konu: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1016/s0040-4020(02)01634-4
  • Dergi Adı: TETRAHEDRON
  • Sayfa Sayıları: ss.1055-1058

Özet

We describe the results of manganese(III) acetate based regioselective oxidation of various alpha,beta-unsaturated cyclopentanones leading to alpha'-acetoxy alpha,beta-unsaturated cyclopentanones in good yields. Products due to monophenyl and diphenyl substituted dimerization have been identified as byproducts of the reaction. (C) 2003 Elsevier Science Ltd. All rights reserved.