The template synthesis, spectral characterizatin and thermal behaviour of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandione


Soenmez M., Sekerci M.

REVIEWS IN INORGANIC CHEMISTRY, vol.26, no.6, pp.553-563, 2006 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 26 Issue: 6
  • Publication Date: 2006
  • Journal Name: REVIEWS IN INORGANIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.553-563
  • Van Yüzüncü Yıl University Affiliated: No

Abstract

A new series of two types of acyclic binuclear Schiff base complexes, prepared by template condensation of N-aminopyrimidine and 2,3-butandione in the presence of Cu-II, Ni-II, Co-II and Zn-II in n-BuOH solution, have been characterized by IR, elemental analyses, electronic spectral data, conductivity and magnetic measurements. From conductivity measurements, it is shown that the complex of Ni-II is electrolyte. All the complexes have sub-normal magnetic moments commensurate with their binuclear nature. The thermal behaviour of the complexes has been studied by t.g. technique.