Synthesis of 3D Sn doped Sb2O3 catalysts with different morphologies and their effects on the electrocatalytic hydrogen evolution reaction in acidic medium

Akınay Y., Kazici H., Akkuş İ. N., Salman F.

CERAMICS INTERNATIONAL, cilt.47, sa.20, ss.29515-29524, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 20
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.ceramint.2021.07.278
  • Dergi Adı: CERAMICS INTERNATIONAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.29515-29524
  • Anahtar Kelimeler: Electrocatalyst, Hydrogen evolution reaction, Antimony oxide, Tin oxide, Catalyst, MOS2 NANOPARTICLES, LITHIUM, PERFORMANCE, GRAPHENE, PHOSPHIDE, NANORODS, ENERGY, ANODE, RAMAN
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

Recently, the design and synthesis of highly effective, abundant and low-cost catalysts to produce molecular hydrogen through the hydrogen evolution reaction (HER) have been studied in a wide range of pHs to replace Pt. In this work, 3D flower-like and rod-like pure Sb2O3 and Sn: Sb2O3 particles by using co-precipitation methods were efficiently synthesized for electro-catalytic energy conversion applications. The morphologies and structure of the synthesized catalysts were investigated extensively. Electrochemical studies were carried out to investigate the catalytic performance of 3D flower-like and rod-like Sn: Sb2O3 and pure Sb2O3 particles for hydrogen evolution reactions (HER) in acidic environments using 0.5 M H2SO4 electrolyte. Among the prepared particles, 3D rod-like Sn: Sb2O3 show excellent electro-catalytic hydrogen evolution reactions (HER) at 0.5 M H2SO4. Moreover, we have obtained the high stability of the electrodes during chronoamperometric studies (current v/s time) approximately 2000 s at constant potential.