Ternary SLE Measurements for the Systems H2O+ZnCl2+Zn(H2PO2)(2) at T=(298, 313 and 333) K

DEMİRCİ S., ADIGÜZEL V., ŞAHİN Ö., Erge H.

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, cilt.44, sa.1, ss.27-32, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 1
  • Basım Tarihi: 2022
  • Doi Numarası: 10.52568/000984/jcsp/44.01.2022
  • Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Analytical Abstracts, Chemical Abstracts Core
  • Sayfa Sayıları: ss.27-32
  • Anahtar Kelimeler: Phase equilibria, Ternary system, Density, Zinc chloride, Zinc hypophosphite, RECIPROCAL QUATERNARY SYSTEM, LIQUID PHASE-EQUILIBRIA, CALCIUM HYPOPHOSPHITE, SOLUBILITY, NA+
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

The solid-liquid equilibrium (SLE) of H2O+ZnCl2+Zn(H2PO2)(2) ternary system at 298, 313 and 333 K have been studied with the use of isothermal method. Solid phase compositions have been determined with Schreinemaker's method. H2O+ZnCl2+Zn(H2PO2)(2) ternary systems have simple eutectic type in 298, 333K. One invariant point, two invariant curves and two crystallization region have been observed in the phase diagrams at 298, 333K. Otherwise, One invariant point, three invariant curves and two crystallization region have been observed in the phase diagrams in 313K. In the crystallization regions; (i) Zn(H2PO2)center dot H2O and ZnCl2, (ii) Zn(H2PO2)(2), Zn(H2PO2)center dot H2O and ZnCl2, (iii) Zn(H2PO2)(2) and ZnCl2 salts have been observed at 298 K, 313K, and 333 K, respectively. In H2O+ZnCl2+Zn(H2PO2)(2) ternary system, the increasing salting-out effect of Zn(H2PO2)(2) on ZnCl2 with temperature.