Chromium based metal-organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane

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Caner N., Yurderi M., Bulut A., Kanberoğlu G. S., Kaya M., Zahmakıran M.

NEW JOURNAL OF CHEMISTRY, cilt.44, ss.12435-12439, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0nj01931c
  • Dergi Adı: NEW JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Biotechnology Research Abstracts, Chimica, EMBASE, DIALNET
  • Sayfa Sayıları: ss.12435-12439
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

Palladium nanoparticles stabilized by an MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H(2)generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min(-1)) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.