Atom transfer rearrangement radical polymerization of diammine-bis(2,4,6-trihalophenolato)copper(II) complexes in the solid state


Goekagac G., Sonsuz M., Sen F., Kisakuerek D.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.61, ss.1222-1228, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 61 Konu: 10
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1515/znb-2006-1006
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Sayfa Sayıları: ss.1222-1228

Özet

The synthesis of the poly(dichloro- or dibromophenylene oxide)s was achieved by the thermal decomposition of diammine-bis(2,4,6-trihalophenolato)copper(II) complexes in the solid state by atom transfer rearrangement radical polymerization. The thermal decomposition was performed either at different temperature ranges, 110-250 degrees C, for 3 h, or at the maximum conversion temperature for different time intervals, 3-48 h. Maximum yields of polymers were obtained at 190 degrees C and 3 h. The polymers were characterized by FTIR, H-1 and C-13 NMR spectroscopy, SEM, TGA and molecular weight determination by viscometrical methods. All the polymers were rigid, having high T-g values between 178 and 189 degrees C. Only small amounts of Cu were detected by AAS.