Highly soluble phthalocyanines with hexadeca tert-butyl substituents

Agirtas M. S.

DYES AND PIGMENTS, cilt.79, sa.3, ss.247-251, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79 Sayı: 3
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.dyepig.2008.03.004
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.247-251
  • Anahtar Kelimeler: phthalocyanines, phthalonitrile derivatives, magnesium, soluble, tert-butyl groups, synthesis, METAL-FREE
  • Van Yüzüncü Yıl Üniversitesi Adresli: Hayır

Özet

A phthalonitrile derivative bearing 2,4-di-tert-butylphenoxy substituents at peripheral positions was synthesized; subsequent cyclotetramerization in DMF and hexanol furnished the desired zinc (II), magnesium (II), copper (II) and nickel (II) phthalocyanines. These metallo-phthalocyanines were highly soluble in solvents such as dichloromethane, chloroform, acetone, ethyl acetate, tetrahydrofuran, diethyl ether, n-hexane and DMF. The structures of the compounds were confirmed by elemental analyses, IR, H-1 NMR, C-13 NMR, electronic spectra and mass spectroscopic methods. (C) 2008 Elsevier Ltd. All rights reserved.