Fluorescence Properties and Electrochemical Behavior of Some Schiff Bases Derived from N-Aminopyrimidine

Gülcan M., Dogru U., Ozturk G., Levent A., Akbaş E.

JOURNAL OF FLUORESCENCE, cilt.24, sa.2, ss.389-396, 2014 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 2
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1007/s10895-013-1303-x
  • Dergi Adı: JOURNAL OF FLUORESCENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.389-396
  • Anahtar Kelimeler: Schiff base, fluorescence, N-Aminopyrimidine, electrochemistry, METAL-COMPLEXES, CRYSTAL-STRUCTURES, LIGAND, DERIVATIVES, CD(II), NI(II), ACID
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

A series of Schiff bases (L (1) , L (2) and L (3) ) were prepared by refluxing aromatic aldehydes with N-Aminopyrimidine derivatives in methanol and ethanol. The structures of synthesized compounds were characterized by FTIR, H-1 NMR, C-13 NMR and microanalysis. The electrochemical behaviors of the Schiff base ligands were also discussed. Moreover, the evaluation of absorption and emission properties of the structures were carried out in five different solvents. The products show visible absorption maxima in the range of 304-576 nm, and emission maxima from 636 to 736 nm in all solvents tested.