Hydroxyl group effect in novel NNN type pyridine based ruthenium (II) complex for the transfer hydrogenation of ketones


Sahin I., Emir S., İSPİR E., Karakaya I., Gümüş S., Ulusoy M., ...More

CATALYSIS COMMUNICATIONS, vol.85, pp.30-33, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 85
  • Publication Date: 2016
  • Doi Number: 10.1016/j.catcom.2016.07.009
  • Journal Name: CATALYSIS COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.30-33
  • Keywords: Transfer hydrogenation, Substituent effect, Ruthenium, NNN ligand, Imino pyridine, PYRAZOLYL-IMIDAZOLYL LIGAND, CATALYSTS BEARING
  • Van Yüzüncü Yıl University Affiliated: Yes

Abstract

The new NNN type pyridine ligands were prepared by using low cost and readily available starting materials and metalated with RuCl2(PPh3)(3) to obtain ruthenium(II) complexes. All structures were illuminated by NMR, HRMS, and FT-IR spectroscopy. The complexes exhibited good catalytic activity in transfer hydrogen reaction of ketones and it was found that a hydroxyl group on beta-position of the pyridine ring had a dramatic effect on the catalyst efficiency. (C) 2016 Elsevier B.V. All rights reserved.