Palladium(0) nanoparticles supported on metal organic framework as highly active and reusable nanocatalyst in dehydrogenation of dimethylamine-borane


Gülcan M. , Zahmakıran M. , ÖZKAR S.

APPLIED CATALYSIS B-ENVIRONMENTAL, vol.147, pp.394-401, 2014 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 147
  • Publication Date: 2014
  • Doi Number: 10.1016/j.apcatb.2013.09.007
  • Title of Journal : APPLIED CATALYSIS B-ENVIRONMENTAL
  • Page Numbers: pp.394-401

Abstract

Palladium(0) nanoparticles supported on the external surface of Cu-3(btc)(2) framework (PdNPs@Cu-3(btc)(2)) were in-situ generated from the reduction of Pd(acac)2 precursor impregnated on the Cu-3(btc)(2) support during the dehydrogenation of dimethylamine-borane in toluene at room temperature. The characterization of PdNPs@Cu-3(btc)(2) by using advanced analytical techniques shows the formation of well-dispersed palladium(0) nanoparticles supported on Cu-3(btc)(2) surface. These new palladium(0) nanoparticles were found to be the most active and the longest-lived nanocatalyst with superior reusability performance in the dehydrogenation of dimethylamine-borane at room temperature. (C) 2013 Elsevier B.V. All rights reserved.