Synthesis of Novel Artemisinin Derivatives and Their Electrochemical Properties


Esen M., Kavak E., Ozok-Arici O., Ulaş B. , DEMİR KIVRAK H., KIVRAK A.

CHEMISTRYSELECT, vol.7, no.19, 2022 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 7 Issue: 19
  • Publication Date: 2022
  • Doi Number: 10.1002/slct.202201223
  • Title of Journal : CHEMISTRYSELECT
  • Keywords: Anode catalyst, Artemisinin, Electrooxidation, Energy, Heterocycles, RSM, Organocatalysis, ANION-EXCHANGE MEMBRANE, FUEL-CELL, HYDRAZINE, ELECTROOXIDATION, METHANOL, CATALYST, BENZOTHIOPHENE, CU

Abstract

In present, new artemisinin-based organic compounds (1-6) are designed and synthesized in excellent yields (up to 97 %) via Steglich Esterification reactions. All new artemisinin derivatives are tested as anode catalysts for hydrazine electrooxidation reactions with electrochemical methods in 1 M KOH/0.5 M N2H4 solution. Hybrid molecule 1 exhibits the best catalytic activity in hydrazine electrooxidation reaction with 2.28 mA cm(-2) value. Moreover, response surface methodology (RSM) is applied to investigate of optimum electrode conditions. By using optimum conditions, hydrazine electrooxidation is obtained as 3.55324 mA cm(-2). As a result, artemisinin-based hybrid compounds may be alternative, and next-generation anode catalyst for direct hydrazine fuel cells.