Multifunctional one-part GBFS geopolymer foams with CDW aggregates and nano-ZnO: Mechanical properties, durability, and antimicrobial performance


Faraji M. F., Hooshyar S., Özkan İ. G. M., Seçkin H., Yılmazoğlu M. U., Türkel İ., ...Daha Fazla

Construction and Building Materials, cilt.547, 2026 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 547
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.conbuildmat.2026.148581
  • Dergi Adı: Construction and Building Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC
  • Anahtar Kelimeler: Antimicrobial performance, Construction and demolition waste aggregates, Freeze-thaw resistance, Ground granulated blast-furnace slag, Nano-zinc oxide, One-part geopolymer foam
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

Despite growing interest in sustainable construction materials, there remains a lack of comprehensive understanding of how construction and demolition waste (CDW) fine aggregates and nano-scale additives jointly influence the performance of one-part geopolymer foams. This study addresses this gap by systematically investigating the combined effects of CDW replacement and nano-ZnO incorporation in ground granulated blast-furnace slag (GBFS)-based geopolymer foams using a 3 × 3 factorial design with 0, 50, and 100 vol% CDW and 0, 1, and 2 wt% nano-ZnO. Fresh behavior, mechanical and transport properties, freeze-thaw resistance, high-temperature response, microstructure, and antimicrobial activity were evaluated. Increasing CDW and nano-ZnO generally reduced flow, density, and ambient strength while increasing water-accessible porosity and sorptivity. Oven-dry density ranged from 1412 to 2194 kg/m³ , and 28-day compressive strength from 20.7 to 43.9 MPa. Nano-ZnO produced a non-monotonic response: 1 wt% caused marked strength loss, whereas 2 wt% yielded partial compressive-strength recovery, indicating competing effects of reaction retardation, agglomeration, pore development, and possible filler/nucleation contributions. Sorptivity correlated strongly with apparent porosity and freeze-thaw mass loss, but weakly with freeze-thaw strength loss, demonstrating different controls on surface scaling and bulk damage. At 800 °C, strength retention increased from 8.5% for the reference to 16.0% for the mixture with 100% CDW and 0 wt% nano-ZnO, while the highest retention was 19.8% for the 2 wt% nano-ZnO mixture without CDW. The strongest antimicrobial response occurred against Candida albicans , with a 28 mm inhibition zone. Overall, CDW content, nano-ZnO dosage, and pore architecture acted as coupled design variables governing multifunctional performance.