Designing of New Thermo Stabile Phthalocyanines: Synthesis, Characterization, and Thermal Studies
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.42, sa.9, ss.1327-1333, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 42 Sayı: 9
- Basım Tarihi: 2012
- Doi Numarası: 10.1080/15533174.2012.680142
- Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1327-1333
- Van Yüzüncü Yıl Üniversitesi Adresli: Evet
Özet
In this study, new phthalonitrile and phthalocyanines were synthesized and characterized. Starting material compound 3 was obtained by reaction of ninhydrin with 4-nitrophthalonitrile. Phthalocyanines 4-8 were prepared by reaction 4-(2-phenoxy-1, 3-dioxo-2, 3-dihydro-1H-inden-2-yloxy) phthalonitrile with corresponding metal salts. Compound 9 was obtained by reaction of phthaocyanine 4 with NaOH. This compound is soluble in water as sodium salts. Thermal properties of compounds 3-8 were investigated by TG and DTA. Thermal stabilities of compounds 4-8 are also reported. The novel compounds were characterized by elemental analysis, FTIR, H-1-NMR, and UV-VIS spectral data.