Designing of New Thermo Stabile Phthalocyanines: Synthesis, Characterization, and Thermal Studies


Ağırtaş M. S. , GUMUS I., Izgi M. S.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.42, ss.1327-1333, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 42 Konu: 9
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1080/15533174.2012.680142
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Sayfa Sayıları: ss.1327-1333

Özet

In this study, new phthalonitrile and phthalocyanines were synthesized and characterized. Starting material compound 3 was obtained by reaction of ninhydrin with 4-nitrophthalonitrile. Phthalocyanines 4-8 were prepared by reaction 4-(2-phenoxy-1, 3-dioxo-2, 3-dihydro-1H-inden-2-yloxy) phthalonitrile with corresponding metal salts. Compound 9 was obtained by reaction of phthaocyanine 4 with NaOH. This compound is soluble in water as sodium salts. Thermal properties of compounds 3-8 were investigated by TG and DTA. Thermal stabilities of compounds 4-8 are also reported. The novel compounds were characterized by elemental analysis, FTIR, H-1-NMR, and UV-VIS spectral data.