Analysis of the dielectric constant, spontaneous polarization and the coersive field close to the phase transitions in ferroelectric K2CoCl4

Yurtseven H., Dogan E.

FERROELECTRICS, cilt.504, sa.1, ss.15-21, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 504 Sayı: 1
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/00150193.2016.1238707
  • Dergi Adı: FERROELECTRICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.15-21
  • Anahtar Kelimeler: Ferroelectricity, dielectric constant, spontaneous polarization, coersive field, K2CoCl4, COMMENSURATE TRANSITION, X-RAY, K2ZNBR4, K2ZNCL4, K2COBR4
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

Temperature dependence of the dielelctric constant epsilon(a) along a axis and the spontaneous polarization P-S is analyzed near the ferroelectric transition (T-C = 182 degrees C) in K2CoCl4. The power-law formula is used for the analysis of the observed data from the literature. Critical exponents we determine from our analysis indicate that K2CoCl4 exhibits a weak first order transition. Coercive field EC is also analyzed using the experimental data which decreases smoothly as the temperature increases toward the transition temperature T-C. It is concluded that the theoretical model(s) with the non-zero applied electric field, can explain the ferroelectric properties of K2CoCl4 close to the phase transitions.