Template synthesis of Fe(III) and Cr(III) acyclic complexes derived from diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one


Sonmez M.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, vol.34, no.4, pp.733-741, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 4
  • Publication Date: 2004
  • Doi Number: 10.1081/sim-120035953
  • Title of Journal : SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Page Numbers: pp.733-741

Abstract

The template synthesis of diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one in the presence of Fe(III) and Cr(III) results in the formation of acyclic complexes of the types [(MLX2)-X-1]X, [(MLX2)-X-2]X, and [Fe-2(L-1)(2)Cl-4]Cl-2.H2O, where M = Fe(III), Cr(III), L-1 (benzyl derivative), or L-2 (diacetyl derivative) are N2O2/ONO acyclic ligands and X = Cl, NO3). The complexes have been characterized by elemental analyses, molar conductance, magnetic measurements, IR, and UV/VIS spectral studies.