Template synthesis of Fe(III) and Cr(III) acyclic complexes derived from diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one

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Atıf İçin Kopyala

Sonmez M.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.34, sa.4, ss.733-741, 2004 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 34 Sayı: 4
• Basım Tarihi: 2004
• Doi Numarası: 10.1081/sim-120035953
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.733-741
• Van Yüzüncü Yıl Üniversitesi Adresli: Hayır

Özet

The template synthesis of diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one in the presence of Fe(III) and Cr(III) results in the formation of acyclic complexes of the types [(MLX2)-X-1]X, [(MLX2)-X-2]X, and [Fe-2(L-1)(2)Cl-4]Cl-2.H2O, where M = Fe(III), Cr(III), L-1 (benzyl derivative), or L-2 (diacetyl derivative) are N2O2/ONO acyclic ligands and X = Cl, NO3). The complexes have been characterized by elemental analyses, molar conductance, magnetic measurements, IR, and UV/VIS spectral studies.