Template synthesis of Fe(III) and Cr(III) acyclic complexes derived from diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one


Sonmez M.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.34, ss.733-741, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 34 Konu: 4
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1081/sim-120035953
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.733-741

Özet

The template synthesis of diacetyl or benzil and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one in the presence of Fe(III) and Cr(III) results in the formation of acyclic complexes of the types [(MLX2)-X-1]X, [(MLX2)-X-2]X, and [Fe-2(L-1)(2)Cl-4]Cl-2.H2O, where M = Fe(III), Cr(III), L-1 (benzyl derivative), or L-2 (diacetyl derivative) are N2O2/ONO acyclic ligands and X = Cl, NO3). The complexes have been characterized by elemental analyses, molar conductance, magnetic measurements, IR, and UV/VIS spectral studies.