Zeolite framework stabilized nickel(0) nanoparticles: Active and long-lived catalyst for hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride

Zahmakiran M. , Ayvali T., Akbayrak S., Caliskan S., Celik D., ÖZKAR S.

CATALYSIS TODAY, cilt.170, sa.1, ss.76-84, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 170 Konu: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.cattod.2010.09.022
  • Sayfa Sayıları: ss.76-84


Among the hydrogen storage materials, ammonia-borane and sodium borohydride appear to be promising candidates as they can release hydrogen on hydrolysis in aqueous solution under mild conditions. Here, we report the development of a cost-effective and highly active nickel(0) nanoparticles catalyst for the hydrolysis of ammonia-borane and sodium borohydride. Nickel(0) nanoparticles confined in zeolite framework were prepared by using our previously established procedure and characterized by ICP-OES, XRD, TEM, HR-TEM, SEM, EDX, XPS, Raman spectroscopy and N-2 adsorption-desorption technique. All the results show that nickel(0) nanoparticles are formed within the framework of zeolite-Y. Nickel(0) nanoparticles confined in zeolite framework are highly active catalyst in the hydrolytic dehydrogenations of sodium borohydride and ammonia-borane. This catalyst is isolable, bottleable, redispersible and reusable. The report also includes the detailed kinetic study of the catalytic hydrolysis of both substrates, ammonia-borane and sodium borohydride depending on the catalyst concentration, substrate concentration, and temperature. (C) 2010 Elsevier B.V. All rights reserved.