Zeolite framework stabilized nickel(0) nanoparticles: Active and long-lived catalyst for hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride

Zahmakiran M., Ayvali T., Akbayrak S., Caliskan S., Celik D., ÖZKAR S.

CATALYSIS TODAY, vol.170, no.1, pp.76-84, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 170 Issue: 1
  • Publication Date: 2011
  • Doi Number: 10.1016/j.cattod.2010.09.022
  • Journal Name: CATALYSIS TODAY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.76-84
  • Van Yüzüncü Yıl University Affiliated: Yes


Among the hydrogen storage materials, ammonia-borane and sodium borohydride appear to be promising candidates as they can release hydrogen on hydrolysis in aqueous solution under mild conditions. Here, we report the development of a cost-effective and highly active nickel(0) nanoparticles catalyst for the hydrolysis of ammonia-borane and sodium borohydride. Nickel(0) nanoparticles confined in zeolite framework were prepared by using our previously established procedure and characterized by ICP-OES, XRD, TEM, HR-TEM, SEM, EDX, XPS, Raman spectroscopy and N-2 adsorption-desorption technique. All the results show that nickel(0) nanoparticles are formed within the framework of zeolite-Y. Nickel(0) nanoparticles confined in zeolite framework are highly active catalyst in the hydrolytic dehydrogenations of sodium borohydride and ammonia-borane. This catalyst is isolable, bottleable, redispersible and reusable. The report also includes the detailed kinetic study of the catalytic hydrolysis of both substrates, ammonia-borane and sodium borohydride depending on the catalyst concentration, substrate concentration, and temperature. (C) 2010 Elsevier B.V. All rights reserved.