The template synthesis, spectral characterization and thermal behaviour of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion

Sonmez M., Sekerci M.

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, cilt.72, sa.3, ss.259-264, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 72 Sayı: 3
  • Basım Tarihi: 2007
  • Doi Numarası: 10.2298/jsc0703259s
  • Dergi Adı: JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.259-264
  • Van Yüzüncü Yıl Üniversitesi Adresli: Hayır

Özet

Anew series of two types of acyclic binuclear Schiff base complexes, prepared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of Ni-II is a 1: 1 type of electrolyte. All the complexes have sub-normal magnetic moments in accordance with their binuclear nature. The thermal behaviour of the complexes was studied by thermogravimetry.