The template synthesis, spectral characterization and thermal behaviour of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion


Sonmez M., Sekerci M.

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, vol.72, no.3, pp.259-264, 2007 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 72 Issue: 3
  • Publication Date: 2007
  • Doi Number: 10.2298/jsc0703259s
  • Title of Journal : JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
  • Page Numbers: pp.259-264

Abstract

Anew series of two types of acyclic binuclear Schiff base complexes, prepared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of Ni-II is a 1: 1 type of electrolyte. All the complexes have sub-normal magnetic moments in accordance with their binuclear nature. The thermal behaviour of the complexes was studied by thermogravimetry.