Studies on the Different Reaction Pathways between 3-Acetyl-5-benzoyl-6-methyl-2-phenyl-4H-pyran-4-one and Alkylamines


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Genç H. , Tan M. , Gümüş S. , Mengeş N. , Bildirici İ. , ŞENER A.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, cilt.31, ss.2633-2636, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 31 Konu: 9
  • Basım Tarihi: 2010
  • Doi Numarası: 10.5012/bkcs.2010.31.9.2633
  • Dergi Adı: BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • Sayfa Sayıları: ss.2633-2636

Özet

3-Acety1-5-benzoy1-6-methy1-2-pheny1-4H-pyran-4-one has been subjected to condensation with a series of primary amines (ethylamine - octylamine) to clarify the proposed mechanism in our previous study. The reactions of the shorter amines of the series (ethylamine - butylamine) yielded unsymmetric pyridinone products, whereas the other amines (pentylamine - octylamine) yielded symmetrical pyridinones. The starting material and the products as well as the intermediates have been subjected to theoretical analysis by quantum chemical calculations at B3LYP/6-3 I G(d,p) level, which provided supporting data for the experimental findings.