Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2',3'-D) pyrrole derivative


Kıvrak A. , YILDIZ H. B. , Gokyer S., Bezgin Carbas B.

TURKISH JOURNAL OF CHEMISTRY, cilt.42, ss.439-448, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 42 Konu: 2
  • Basım Tarihi: 2018
  • Doi Numarası: 10.3906/kim-1709-33
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.439-448

Özet

A novel alkoxy-bridged dithieno (3, 2-B:2',3'-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2',3'-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectro-chemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.