Synthesis of Some Novel Pyrimidine Derivatives and Investigation of their Electrochemical Behavior

Akbaş E., Levent A., Gümüş S., SUMER M. R., AKYAZI I.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, cilt.31, sa.12, ss.3632-3638, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 12
  • Basım Tarihi: 2010
  • Doi Numarası: 10.5012/bkcs.2010.31.12.3632
  • Dergi Adı: BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3632-3638
  • Anahtar Kelimeler: 2-Iminopyrimidines, 2-Thioxopyrimidine, Biginelli cyclocondensation, Electrochemical properties, SEMIEMPIRICAL METHODS, OPTIMIZATION, PARAMETERS, EXCHANGE, LIGAND
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

2-Iminopyrimidines (1a-e) and 2-thioxopyrimidine (2) were synthesized using the Biginelli three component cyclocondensation reaction of an appropriate beta-diketone, arylaldehyde, and guanidine (for 1a-e) or thiourea (for 2). The electrochemical properties of the novel systems were investigated by CV and DPV. Moreover, B3LYP/6-31G(d,p) method was applied to the present structures in order to gather some structural and physicochemical data.