Synthesis of Some Novel Pyrimidine Derivatives and Investigation of their Electrochemical Behavior


Akbaş E. , Levent A., Gümüş S. , SUMER M. R. , AKYAZI I.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, cilt.31, ss.3632-3638, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 31 Konu: 12
  • Basım Tarihi: 2010
  • Doi Numarası: 10.5012/bkcs.2010.31.12.3632
  • Dergi Adı: BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • Sayfa Sayıları: ss.3632-3638

Özet

2-Iminopyrimidines (1a-e) and 2-thioxopyrimidine (2) were synthesized using the Biginelli three component cyclocondensation reaction of an appropriate beta-diketone, arylaldehyde, and guanidine (for 1a-e) or thiourea (for 2). The electrochemical properties of the novel systems were investigated by CV and DPV. Moreover, B3LYP/6-31G(d,p) method was applied to the present structures in order to gather some structural and physicochemical data.