Synthesis of Some Novel Pyrimidine Derivatives and Investigation of their Electrochemical Behavior
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, cilt.31, sa.12, ss.3632-3638, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 31 Sayı: 12
- Basım Tarihi: 2010
- Doi Numarası: 10.5012/bkcs.2010.31.12.3632
- Dergi Adı: BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.3632-3638
- Anahtar Kelimeler: 2-Iminopyrimidines, 2-Thioxopyrimidine, Biginelli cyclocondensation, Electrochemical properties, SEMIEMPIRICAL METHODS, OPTIMIZATION, PARAMETERS, EXCHANGE, LIGAND
- Van Yüzüncü Yıl Üniversitesi Adresli: Evet
Özet
2-Iminopyrimidines (1a-e) and 2-thioxopyrimidine (2) were synthesized using the Biginelli three component cyclocondensation reaction of an appropriate beta-diketone, arylaldehyde, and guanidine (for 1a-e) or thiourea (for 2). The electrochemical properties of the novel systems were investigated by CV and DPV. Moreover, B3LYP/6-31G(d,p) method was applied to the present structures in order to gather some structural and physicochemical data.