Synthesis and characterization of heterocyclic Schiff base and its complexes with Cu(II), Ni(II), Co(II), Zn(II), and Cd(II)

Sönmez M., Bayram M. R., Çelebi M.

JOURNAL OF COORDINATION CHEMISTRY, vol.62, no.16, pp.2728-2735, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 62 Issue: 16
  • Publication Date: 2009
  • Doi Number: 10.1080/00958970902915582
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.2728-2735
  • Keywords: N-aminopyrimidine-2-thione, heterocyclic Schiff base, Complexes, COPPER(II), NICKEL(II), COBALT(II), ZINC(II)
  • Van Yüzüncü Yıl University Affiliated: Yes

Abstract

A new Schiff base, {1-[(2-hydroxy-naphthalen-1-ylmethylene)-amino]-4-phenyl-2-thioxo-1, 2-dihydro-pyrimidin-5-yl}-phenyl-methanone, has been synthesized from N-amino pyrimidine-2-thione and 2-hydroxynaphthaldehyde. Metal complexes of the Schiff base were prepared from acetate/chloride salts of Cu(II), Co(II), Ni(II), Zn(II), and Cd(II) in methanol. The chemical structures of the Schiff-base ligand and its metal complexes were confirmed by elemental analyses, IR, 13C-NMR, 1H-NMR, API-ES, UV-Visible spectroscopy, magnetic susceptibility, and thermogravimetric analyses. The electronic spectral data and magnetic moment measurements suggest mononuclear octahedral and mononuclear or binuclear square planar structures for the metal complexes. In light of these results, it was suggested that this ligand coordinates to each metal atom by hydroxyl oxygen, azomethine nitrogen, and thione sulfur to form octahedral complexes with Cd(II) and Zn(II).