Synthesis and characterization of novel symmetrical phthalocyanines substituted with four benzo[d] [1,3] dioxol-5-ylmethoxy groups

Agirtas M. S.

INORGANICA CHIMICA ACTA, vol.360, no.7, pp.2499-2502, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 360 Issue: 7
  • Publication Date: 2007
  • Doi Number: 10.1016/j.ica.2006.12.029
  • Journal Name: INORGANICA CHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2499-2502
  • Keywords: phthalocyanines, phthalonitrile derivatives, metallophthalocyanine, monomer, complexes, METAL-FREE, COMPLEXES, ELECTROCHEMISTRY, SPECTROSCOPY, MACROCYCLES
  • Van Yüzüncü Yıl University Affiliated: No

Abstract

Metal (Zn, Cu, Co, Mg) phthalocyanines substituted with four benzo [d] [1, 3] dioxol-5-ylmethoxy unit through oxy-bridges have been synthesized from phthalonitrile derivative, 4-(benzo [d] [1,3] dioxol-5-ylmethoxy) phthalonitrile. Benzo [d] [1,3] dioxol-5-ylmethoxy substituted Pcs showed the enhanced solubility in organic solvents. The newly prepared compounds have been characterized by elemental analyses, IR, UV-Vis, H-1 NMR spectra. (c) 2006 Elsevier B.V. All rights reserved.