GLOBAL SUMMIT ON ADVANCED MATERIALS & SUSTAINABLE ENERGY (G-AMSE22), Van, Turkey, 3 - 04 October 2022, pp.82-86
ABSTRACT: In this study, Ru (0) nanoclusters
supported by different solid support
materials such as halloysite (HS), were
prepared by storing ruthenium (III) salt in
the aqueous phase on the solid support
surface and then reducing it using NaBH4.
The catalytic activity of the prepared Ru@
HS, catalyst in the hydrogen production
from the methanolysis of hydrazineborane was tested and it was determined
that Ru@HS was catalyst foundto be
active. The experimental method followed
in the preparation of Ru(0) nanoclusters
was carried out using the parameters of
solvent and reductant. As a result of the
processes carried out, catalytic material
was characterized by techniques such as
inductively coupled mass spectroscopy
(ICP-MS), powder-X-ray diffraction (P-XRD).
The catalytic activity of HS stabilized Ru
(0) nanoclusters and the kinetics of the
hydrazine-borane methanolysis reaction
in the presence of Ru@HS catalyst were
investigated depending on the catalyst
concentrations .