Chromium based metal-organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane

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Caner N., Yurderi M., Bulut A., Kanberoğlu G. S. , Kaya M., Zahmakıran M.

NEW JOURNAL OF CHEMISTRY, vol.44, pp.12435-12439, 2020 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 44
  • Publication Date: 2020
  • Doi Number: 10.1039/d0nj01931c
  • Title of Journal : NEW JOURNAL OF CHEMISTRY
  • Page Numbers: pp.12435-12439


Palladium nanoparticles stabilized by an MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H(2)generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min(-1)) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.