Chromium based metal–organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane†


Kanberoğlu G. S. , Zahmakıran M.

NEW JOURNAL OF CHEMISTRY, cilt.1, ss.1-13, 2020 (SCI Expanded İndekslerine Giren Dergi)

  • Cilt numarası: 1
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0nj01931c
  • Dergi Adı: NEW JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1-13

Özet

Palladium nanoparticles stabilized by an MIL-101 metal–organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H2 generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min−1) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.