Synthesis of metallophthalocyanines with four oxy-2,2-diphenylacetic acid substituents and their structural and electronic properties


Abdalrazaq S. M. , Cabir B., Gümüş S., Ağırtaş M. S.

HETEROCYCLIC COMMUNICATIONS, vol.22, no.5, pp.275-280, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 22 Issue: 5
  • Publication Date: 2016
  • Doi Number: 10.1515/hc-2016-0120
  • Journal Name: HETEROCYCLIC COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.275-280
  • Keywords: aggregation, electronic structure, phthalocyanine, synthesis, PHTHALOCYANINES, ANTIOXIDANT
  • Van Yüzüncü Yıl University Affiliated: Yes

Abstract

The synthesis and characterization of new copper-, magnesium-and cobalt-phthalocyanine complexes are reported. It appears that these complexes are not aggregated in THF in the concentration range of 1 x 10(-5)-1 x 10(-6) m. Additional structural and electronic data about the new complexes were obtained by calculations with the application of density functional theory at B3LYP/6-31G(d, p) level.