Nanocatalytic Architecture for the Selective Dehydrogenation of Formic Acid


Bağuç İ. B., Kanberoğlu G., Yurderi M., Bulut A., Çelebi M., Zahmakıran M., ...More

in: Nanoparticles in Catalysis: Advances in Synthesis and Applications, Karine Philippot,Alain Roucoux, Editor, John Wiley & Sons, West Sussex, UK , West-Bromwich, pp.279-305, 2021

  • Publication Type: Book Chapter / Chapter Research Book
  • Publication Date: 2021
  • Publisher: John Wiley & Sons, West Sussex, UK 
  • City: West-Bromwich
  • Page Numbers: pp.279-305
  • Editors: Karine Philippot,Alain Roucoux, Editor
  • Van Yüzüncü Yıl University Affiliated: Yes

Abstract

Today, the advancement of secure and effectual hydrogen (H2) storage is a crucial concern in the hydrogen-based energy economy, which would aid the changeover from fossil fuel-based energy to renewable energy. In this respect, an increasing number of studies are still reported for testing various solid materials such as carbon nanotubes, zeolites, metal–organic framework (MOF) materials, organic polymers, boron hydrides (LiBH4, NaBH4, etc.), and boron–nitrogen compounds (NH3BH3, N2H4BH3, NH3B3H7, etc.) in the chemical hydrogen storage . Additionally, recent studies have shown that the liquid organic hydrogen carrier (LOHC) strategy is also an effective way for storing hydrogen by hydrogenation/dehydrogenation cycle storage system. Among various LOHC materials, formic acid (FA; HCOOH), which is one of the major stable products formed in biomass processing and contains 4.4 wt% of H2, has recently attracted significant attention as a potential hydrogen carrier for fuel cells designed toward portable use because of its inherent following advantages