Metal ion selectivity feature and synthesis of axially bis(3-(1,1-diphenylethoxy)propanoate) substitute silicon phthalocyanine

Ağırtaş M. S., Güngördü Solğun D.

Phosphorus, Sulfur and Silicon and the Related Elements, cilt.201, sa.4, ss.409-415, 2026 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 201 Sayı: 4
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1080/10426507.2025.2596812
  • Dergi Adı: Phosphorus, Sulfur and Silicon and the Related Elements
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Sayfa Sayıları: ss.409-415
  • Anahtar Kelimeler: Fe3+, phthalocyanine, selective, Synthesis, UV-visible
  • Van Yüzüncü Yıl Üniversitesi Adresli: Evet

Özet

In this study, first 3-(1,1-diphenylethoxy) propionic acid was obtained from the reaction of 1,1-diphenylethanol and 3-chloropropionic acid. Bis(3-(1,1-diphenylethoxy) propanoate) silicon phthalocyanine was obtained from the reaction of 3-(1,1-diphenylethoxy) propionic acid with SiPcCl2. The newly prepared compounds were characterized by 1H NMR, FT-IR, mass spectrometry and UV-vis spectroscopy. The singlet oxygen quantum yield for silicon phthalocyanine, which has the potential to be a photosensitizer, was determined as 0.13 by chemical method. Finally, metal ion selectivity of bis(3-(1,1-diphenylethoxy) propanoate) silicon phthalocyanine was determined by UV absorption spectroscopy. A total of 11 metal ions (Mg2+, Mn2+, Na+, Ni2+, Zn2+, Fe3+, Ba2+, Cd2+, Cu2+, Co2+, and Ag+) were used for testing. Of these metal ions, only the Fe3+ ion was selectively determined.